Look up a rail journey from Barcelona to Leon and nearly all the journey options will involve traveling via Madrid and making a transfer between Atoch and Chamartin stations in the Spanish capital; particularly now that the high speed line is now fully open between Madrid and Leon.
However, there is a daily direct train available, which avoids the needs to make a connection across Madrid; and it tends to be cheaper too.
When travelling between most cities by train there is only one logical option, though on other journeys there is a choice between different trains or alternative routes. If different options are available you can use the info to decide which is best for you.
7hr 55min
Daily
1 x train per day
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This is one of more than 100 train travel guides available on ShowMeTheJourney, which will make it easier to take the train journeys you want or need to make. As always, all images were captured on trips taken by ShowMeTheJourney.